Preparation, Characterization, Theoretical Treatment and Adsorption on SurfacesN5AcyclicImmobilizes on Silica Gel for Removal of Some Toxic Metals.

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dc.contributor.authorAL- Obaidi, Omar Hamad Shehab
dc.contributor.authorAl-Jibouri, Mahmoud N
dc.date.accessioned2015-04-25T07:01:01Z
dc.date.available2015-04-25T07:01:01Z
dc.date.issued2014-01
dc.description.abstractA series of transition elements complexes with [2,6-diacetimino-pheylenediamine – [2,2,diyl] pyridine] of the general formula [MLCl]Clx, (where M= Cr(III), Pb(II), Zn(II) and Cd(II), x= 2 for Cr(III)) respectively have been synthesized and fully characterized on the bases of C.H.N.M, elemental analysis, 13C NMR, UV- Visible and FTIR spectra , in addition the structure of complexes was characterized by magnetic moments and molar conductance in DMF solution ,and molar ratio of complexes were also determined. On the basis ofelectronic spectral studies .All complexes have an octahedral geometry around the metal center in (1:1) (L:M). A theoretical treatment of the formation of complexes in the gas phase was studied, this was done using the HYPERCHEM-6 program for the Molecular mechanics and Semiempirical calculations. The batch adsorption method has applied on N5 polydentate ligand to remove the selected toxic metal ions from waste water after immobilization the newly n5-ligand on silica gel by physic-chemical method.en_US
dc.identifier.citationAL- Obaidi Omar Hamad Shehab, Al-Jibouri Mahmoud N. Preparation, Characterization, Theoretical Treatment and Adsorption on SurfacesN5AcyclicImmobilizes on Silica Gel for Removal of Some Toxic Metals. International Journal of Biochemistry Research & Review 2014 Jan-Feb ; 4 (1) : 28-42.en_US
dc.identifier.urihttps://imsear.searo.who.int/handle/123456789/157864
dc.language.isoenen_US
dc.source.urihttps://www.sciencedomain.org/abstract.php?iid=279&id=3&aid=2219en_US
dc.subjectPreparationen_US
dc.subjectcharacterizationen_US
dc.subjecttheoretical treatmenten_US
dc.subjectadsorptionen_US
dc.subjectimmobilizesen_US
dc.subjecttoxic metalsen_US
dc.titlePreparation, Characterization, Theoretical Treatment and Adsorption on SurfacesN5AcyclicImmobilizes on Silica Gel for Removal of Some Toxic Metals.en_US
dc.typeArticleen_US
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