Polaron hopping in some biomolecular solids and their charge transfer complexes.

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2008-12-26
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The solid state spectroscopy of charge transfer complexes of biomolecules such as fatty acids, tripalmitin, lysozyme. folic acid, beta-carotene, cytochrome c, valinomycin and gramicidin has been carried out. The absorption coefficient is related with electronic conductivity. A half-power beta density is found common among these macromolecular solids, indicating photon-induced polaron hopping or hopping of a charge carrier between two branches of a polariton. Band gap vs full width at half-maximum of the mid-IR peak also reveals a linear relation.
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Solanki GK, Amin A, Padhiyar A, Ray AK, Oza AT. Polaron hopping in some biomolecular solids and their charge transfer complexes. Indian Journal of Biochemistry & Biophysics. 2008 Dec; 45(6): 421-9